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The natural direct metabolite of tryptamine, N,N-dimethyltryptamine (DMT) belongs to a class of serotonergic psychedelics (Table 1). Biosynthesis of DMT from tryptamine requires double methylation reactions catalyzed by indolethylamine-N-methyltransferase. The biosynthesis of DMT begins with the decarboxylation of tryptophan that leads to the production of tryptamine.

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